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31.
Yinghui Sun Guojie Zhang Haizhu Cheng Jun Liu Guoqiang Li 《International Journal of Hydrogen Energy》2021,46(1):531-542
The mechanism and kinetic features of dry reforming with methane (DRM) over Ca promoted 1Co–1Ce/AC-N catalyst was investigated. The mechanistic pathway studies have conducted by FTIR and XPS analysis, structure-activity correlations demonstrated the CH4 and CO2 could adsorb on catalyst active sites and generate intermediate CHx, OH and CHxO, continue to generate CO and H2 and then desorbed from active sites. Moreover, CH4 could also oxidized by Ce4+ and CO2 reduced by Ce3+, the same content of Ce4+ and Ce3+ on promoted catalyst greatly improved the reaction rate. The kinetic of dry reforming with methane was examined for temperature between 650 and 850 at 800 °C. The research was carried out by changing the CH4/CO2 ratios between 0.3 and 3.0. The obtained experiment data were fitted by three typical kinetic models (Power Law, Eley-Rideal and Langmuir-Hinshelwood), the fitting results demonstrated that the best prediction of reforming rates can provided by Langmuir-Hinshelwood model for the reaction temperatures between 650 and 800 °C. Moreover, activation energies of methane and carbon dioxide consumption were ?117 and ?47 kJ/mol, indicating that much higher energy barrier is needed for methane activation compared to carbon dioxide. 相似文献
32.
针对连续查询位置服务中构造匿名区域未考虑语义位置信息导致敏感隐私泄露问题,通过设计[(K,θ)]-隐私模型,提出一种路网环境下面向连续查询的敏感语义位置隐私保护方案。该方案利用Voronoi图将城市路网预先划分为独立的Voronoi单元,依据用户的移动路径和移动速度,选择具有相似特性的其他[K-1]个用户,构建匿名用户集;利用匿名用户集用户设定的敏感语义位置类型和语义安全阈值,以及用户所处语义位置的Voronoi单元,构建满足[(K,θ)]-隐私模型的语义安全匿名区域,可以同时防止连续查询追踪攻击和语义推断攻击。实验结果表明,与SCPA算法相比,该方案在隐私保护程度上提升约15%,系统开销上降低约20%。 相似文献
33.
Journal of Computer Science and Technology - In mobile social networks, next point-of-interest (POI) recommendation is a very important function that can provide personalized location-based... 相似文献
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为了解决基于位置的服务(LBS)和增强现实(AR)技术快速发展带来的用户位置隐私泄露的隐患,分析了现有的位置隐私保护方法的优缺点,提出基于位置安全性的位置隐私保护方法。将区域安全度和伪装区域引入该方法中,将提示某区域是否需要保护这一度量标准定义为区域安全度,非安全区域(即需要给予保护的区域)的区域安全度设置为1,安全区域(即不需要保护的区域)设置为0,通过扩大区域安全度和识别等级来计算位置安全度。实验结果表明,该方法与未引入位置安全性的方法相比降低了平均定位误差,提高了平均安全性,从而有效地保护了用户的位置隐私,提高了LBS的服务质量。 相似文献
36.
《Contact lens & anterior eye》2020,43(5):507-511
PurposeSince tear film stability can be affected by fluorescein, the Dry Eye Workshop (DEWSII) recommended non-invasive measurement of tear breakup time (NIBUT). The aim of this study was to investigate the agreement and repeatability of four different instruments in the measurement of NIBUT.Methods72 participants (mean 24.2 ± 3.6 years) were recruited for this multi-centre, cross-sectional study. NIBUT was measured three times from one eye using each of the instruments in randomized order on two separate sessions during a day, separated by at least 2 h. NIBUT was performed at three sites (Switzerland, Germany and UK) using three subjective instruments, Tearscope Plus (Keeler, Windsor, UK) (TS), Polaris (bon Optic, Lübeck, Germany) (POL), EasyTear Viewplus (Easytear, Rovereto, Italy) (ET) and the objective Keratograph 5 M (Oculus Optikgeräte GmbH, Wetzlar, Germany) (KER). As the latter instrument only analyses for 24 s, all data was capped at this value.ResultsNIBUT measurements (average of both sessions) between the four instruments were not statistically significantly different: TS (median 10.4, range 2.0–24.0 s), POL (10.1, 1.0–24.0 s), ET (10.6, 1.0–24.0 s) and KER (11.1, 2.6–24.0 s) (p = 0.949). The objective KER measures were on average (1.2 s ± 9.6 s, 95 % confidence interval) greater than the subjective evaluations of NIBUT with the other instruments (mean difference 0.4 s ± 7.7 s, 95 % confidence interval), resulting in a higher limits of agreement. The slope was -0.08 to 0.11 indicating no bias in the difference between instruments with the magnitude of the NIBUT. Repeated measurements from the two sessions were not significantly different for TS (p = 0.584), POL (p = 0.549), ET (p = 0.701) or KER (p = 0.261).ConclusionsThe four instruments evaluated for their measurement of tear stability were reasonably repeatable and give similar average results. 相似文献
37.
《International Journal of Hydrogen Energy》2022,47(8):5337-5353
CO2 utilization through the activation of ethane, the second largest component of natural and shale gas, to produce syngas, has garnered significant attention in recent years. This work provides a comparative study of Ni catalysts supported on alumina, alumina modified with CaO and MgO, as well as alumina modified with La2O3 for the reaction of dry ethane reforming. The calcined, reduced and spent catalysts were characterized employing XRD, N2 physisorption, H2-TPR, CO2-TPD, TEM, XPS and TPO. The modification of the alumina support with alkaline earth oxides (MgO and CaO) and lanthanide oxides (La2O3), as promoters, is found to improve the dispersion of Ni, enhance the catalyst's basicity and metal-support interaction, as well as influence the nature of carbon deposition. The Ni catalyst supported on modified alumina with La2O3 exhibits a relatively stable syngas yield during 8 h of operation, while H2 and CO yields decrease substantially for Ni/Al2O3. 相似文献
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39.
《International Journal of Hydrogen Energy》2022,47(14):9058-9070
Production of methanol, as a green energy, from syngas is coming into focus. However, natural gas based methanol plants, which are used steam reforming of methane for syngas production, have a high CO2 emission resulting in the global warming. In this study, a novel process for methanol synthesis is proposed to reduce CO2 emission. In this regard, natural gas and flue gas are fed to a parallel-series system with tri and dry reforming of methane for syngas production with the optimized stoichiometric number. Then, the produced syngas is converted to methanol in a reactor. Finally, the produced methanol is purified by two distillation towers. The proposed method is compared to a referenced method in the view of technological, economic and environmental metrics. The techno-economic-environmental analysis of the processes reveals that not only the proposed method, as compared to the referenced one, increases CO2 conversion from 20.93% to 99.22%, but also it is more economical and environmentally friendly. In addition, the global warming potential of the proposed method is almost 60% lower than that for the referenced method due to the lower CO2 emission. Therefore, the proposed method can save above MUS$ 8 a year by CO2 capture. 相似文献
40.
针对无法获得可靠羽流流向信息不利于实现羽流追踪的问题,提出了一种基于决策树的羽流追踪移动机器人自主决策方法。该方法通过移动机器人两侧的浓度传感器采集到的浓度信息,利用追踪的行为规则建立决策树模型,获得行为决策信息,使机器人高效地追踪到羽流并精确地定位。由于浓度变化关系蕴含了羽流的流向及流速信息,从而取代了传统方法中流向及流速传感器。在扩散环境下,通过移动机器人羽流追踪实验,实现了良好的源定位效果。 相似文献